LrgpV1, Main, Exploration, bibRecord, 000B65

Efficient and Complementary Methods Offering Access to Synthetically Valuable 1,2‐Dibromobenzenes

Identifieur interne : 000B65 ( Main/Exploration ); précédent : 000B64; suivant : 000B66

Efficient and Complementary Methods Offering Access to Synthetically Valuable 1,2‐Dibromobenzenes

Auteurs : Vincent Diemer [France] ; Frédéric R. Leroux [France] ; Françoise Colobert [France]

Source :

European Journal of Organic Chemistry [ 1434-193X ] ; 2011-01.

RBID : ISTEX:00B8AE2CC871EF51AC29C430B984F3C1652C9528

English descriptors

KwdEn :
- Angew, Anhydrous, Aniline, Aryne, Biaryl, Boronic, Boronic ester, Calcd, Cdcl3, Chem, Colobert, Colorless, Column chromatography, Cyclohexane, Diazonium, Diazonium salt, Diemer, Dropwise, Ester, Et2o, Functionalized, Further purification, Gmbh, Hexane, Hrms, Kgaa, Knochel, Larock, Leroux, Lett, Meoh, Metalation, Mmol, Nucleophilic, Och3, Organic layer, Organic layers, Permutation, Precursor, Regioselective, Spectroscopic, Spectroscopic data, Tetrahedron, Tetrahedron lett, Tmscl, Toluene, Verlag, Verlag gmbh, Weinheim.
Teeft :
- Angew, Anhydrous, Aniline, Aryne, Biaryl, Boronic, Boronic ester, Calcd, Cdcl3, Chem, Colobert, Colorless, Column chromatography, Cyclohexane, Diazonium, Diazonium salt, Diemer, Dropwise, Ester, Et2o, Functionalized, Further purification, Gmbh, Hexane, Hrms, Kgaa, Knochel, Larock, Leroux, Lett, Meoh, Metalation, Mmol, Nucleophilic, Och3, Organic layer, Organic layers, Permutation, Precursor, Regioselective, Spectroscopic, Spectroscopic data, Tetrahedron, Tetrahedron lett, Tmscl, Toluene, Verlag, Verlag gmbh, Weinheim.

Abstract

1,2‐Dibromobenzenes are highly valuable precursors for various organic transformations, in particular, reactions based on the intermediate formation of benzynes. This report describes short sequences for the synthesis of various derivatives based on regioselective bromination, ortho‐metalation, and halogen/metal permutations. 1,2‐Dibromo‐3‐iodobenzene (2f), 1,2‐dibromo‐4‐iodobenzene (4c), and 2,3‐dibromo‐1,4‐diiodobenzene (5e) act as intermediates in these syntheses.

Url:

https://api.istex.fr/document/00B8AE2CC871EF51AC29C430B984F3C1652C9528/fulltext/pdf

DOI: 10.1002/ejoc.201001217

Affiliations:

Links toward previous steps (curation, corpus...)

to stream Istex, to step Corpus: 000C12
to stream Istex, to step Curation: 000C12
to stream Istex, to step Checkpoint: 000087
to stream Main, to step Merge: 000C90
to stream Main, to step Curation: 000B65

Le document en format XML

<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title xml:lang="en">Efficient and Complementary Methods Offering Access to Synthetically Valuable 1,2‐Dibromobenzenes</title>
<author><name sortKey="Diemer, Vincent" sort="Diemer, Vincent" uniqKey="Diemer V" first="Vincent" last="Diemer">Vincent Diemer</name>
</author>
<author><name sortKey="Leroux, Frederic R" sort="Leroux, Frederic R" uniqKey="Leroux F" first="Frédéric R." last="Leroux">Frédéric R. Leroux</name>
</author>
<author><name sortKey="Colobert, Francoise" sort="Colobert, Francoise" uniqKey="Colobert F" first="Françoise" last="Colobert">Françoise Colobert</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:00B8AE2CC871EF51AC29C430B984F3C1652C9528</idno>
<date when="2011" year="2011">2011</date>
<idno type="doi">10.1002/ejoc.201001217</idno>
<idno type="url">https://api.istex.fr/document/00B8AE2CC871EF51AC29C430B984F3C1652C9528/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">000C12</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000C12</idno>
<idno type="wicri:Area/Istex/Curation">000C12</idno>
<idno type="wicri:Area/Istex/Checkpoint">000087</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000087</idno>
<idno type="wicri:doubleKey">1434-193X:2011:Diemer V:efficient:and:complementary</idno>
<idno type="wicri:Area/Main/Merge">000C90</idno>
<idno type="wicri:Area/Main/Curation">000B65</idno>
<idno type="wicri:Area/Main/Exploration">000B65</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a" type="main" xml:lang="en">Efficient and Complementary Methods Offering Access to Synthetically Valuable 1,2‐Dibromobenzenes</title>
<author><name sortKey="Diemer, Vincent" sort="Diemer, Vincent" uniqKey="Diemer V" first="Vincent" last="Diemer">Vincent Diemer</name>
<affiliation wicri:level="4"><country>France</country>
<placeName><settlement type="city">Strasbourg</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Alsace (région administrative)</region>
</placeName>
<orgName type="university">Université de Strasbourg</orgName>
</affiliation>
</author>
<author><name sortKey="Leroux, Frederic R" sort="Leroux, Frederic R" uniqKey="Leroux F" first="Frédéric R." last="Leroux">Frédéric R. Leroux</name>
<affiliation wicri:level="1"><country wicri:rule="url">France</country>
</affiliation>
<affiliation wicri:level="4"><country>France</country>
<placeName><settlement type="city">Strasbourg</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Alsace (région administrative)</region>
</placeName>
<orgName type="university">Université de Strasbourg</orgName>
</affiliation>
<affiliation wicri:level="1"><country wicri:rule="url">France</country>
</affiliation>
</author>
<author><name sortKey="Colobert, Francoise" sort="Colobert, Francoise" uniqKey="Colobert F" first="Françoise" last="Colobert">Françoise Colobert</name>
<affiliation wicri:level="4"><country>France</country>
<placeName><settlement type="city">Strasbourg</settlement>
<region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Alsace (région administrative)</region>
</placeName>
<orgName type="university">Université de Strasbourg</orgName>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j" type="main">European Journal of Organic Chemistry</title>
<title level="j" type="alt">EUROPEAN JOURNAL OF ORGANIC CHEMISTRY</title>
<idno type="ISSN">1434-193X</idno>
<idno type="eISSN">1099-0690</idno>
<imprint><biblScope unit="vol">2011</biblScope>
<biblScope unit="issue">2</biblScope>
<biblScope unit="page" from="327">327</biblScope>
<biblScope unit="page" to="340">340</biblScope>
<biblScope unit="page-count">14</biblScope>
<publisher>WILEY‐VCH Verlag</publisher>
<pubPlace>Weinheim</pubPlace>
<date type="published" when="2011-01">2011-01</date>
</imprint>
<idno type="ISSN">1434-193X</idno>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">1434-193X</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Angew</term>
<term>Anhydrous</term>
<term>Aniline</term>
<term>Aryne</term>
<term>Biaryl</term>
<term>Boronic</term>
<term>Boronic ester</term>
<term>Calcd</term>
<term>Cdcl3</term>
<term>Chem</term>
<term>Colobert</term>
<term>Colorless</term>
<term>Column chromatography</term>
<term>Cyclohexane</term>
<term>Diazonium</term>
<term>Diazonium salt</term>
<term>Diemer</term>
<term>Dropwise</term>
<term>Ester</term>
<term>Et2o</term>
<term>Functionalized</term>
<term>Further purification</term>
<term>Gmbh</term>
<term>Hexane</term>
<term>Hrms</term>
<term>Kgaa</term>
<term>Knochel</term>
<term>Larock</term>
<term>Leroux</term>
<term>Lett</term>
<term>Meoh</term>
<term>Metalation</term>
<term>Mmol</term>
<term>Nucleophilic</term>
<term>Och3</term>
<term>Organic layer</term>
<term>Organic layers</term>
<term>Permutation</term>
<term>Precursor</term>
<term>Regioselective</term>
<term>Spectroscopic</term>
<term>Spectroscopic data</term>
<term>Tetrahedron</term>
<term>Tetrahedron lett</term>
<term>Tmscl</term>
<term>Toluene</term>
<term>Verlag</term>
<term>Verlag gmbh</term>
<term>Weinheim</term>
</keywords>
<keywords scheme="Teeft" xml:lang="en"><term>Angew</term>
<term>Anhydrous</term>
<term>Aniline</term>
<term>Aryne</term>
<term>Biaryl</term>
<term>Boronic</term>
<term>Boronic ester</term>
<term>Calcd</term>
<term>Cdcl3</term>
<term>Chem</term>
<term>Colobert</term>
<term>Colorless</term>
<term>Column chromatography</term>
<term>Cyclohexane</term>
<term>Diazonium</term>
<term>Diazonium salt</term>
<term>Diemer</term>
<term>Dropwise</term>
<term>Ester</term>
<term>Et2o</term>
<term>Functionalized</term>
<term>Further purification</term>
<term>Gmbh</term>
<term>Hexane</term>
<term>Hrms</term>
<term>Kgaa</term>
<term>Knochel</term>
<term>Larock</term>
<term>Leroux</term>
<term>Lett</term>
<term>Meoh</term>
<term>Metalation</term>
<term>Mmol</term>
<term>Nucleophilic</term>
<term>Och3</term>
<term>Organic layer</term>
<term>Organic layers</term>
<term>Permutation</term>
<term>Precursor</term>
<term>Regioselective</term>
<term>Spectroscopic</term>
<term>Spectroscopic data</term>
<term>Tetrahedron</term>
<term>Tetrahedron lett</term>
<term>Tmscl</term>
<term>Toluene</term>
<term>Verlag</term>
<term>Verlag gmbh</term>
<term>Weinheim</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract">1,2‐Dibromobenzenes are highly valuable precursors for various organic transformations, in particular, reactions based on the intermediate formation of benzynes. This report describes short sequences for the synthesis of various derivatives based on regioselective bromination, ortho‐metalation, and halogen/metal permutations. 1,2‐Dibromo‐3‐iodobenzene (2f), 1,2‐dibromo‐4‐iodobenzene (4c), and 2,3‐dibromo‐1,4‐diiodobenzene (5e) act as intermediates in these syntheses.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
</country>
<region><li>Alsace (région administrative)</li>
<li>Grand Est</li>
</region>
<settlement><li>Strasbourg</li>
</settlement>
<orgName><li>Université de Strasbourg</li>
</orgName>
</list>
<tree><country name="France"><region name="Grand Est"><name sortKey="Diemer, Vincent" sort="Diemer, Vincent" uniqKey="Diemer V" first="Vincent" last="Diemer">Vincent Diemer</name>
</region>
<name sortKey="Colobert, Francoise" sort="Colobert, Francoise" uniqKey="Colobert F" first="Françoise" last="Colobert">Françoise Colobert</name>
<name sortKey="Leroux, Frederic R" sort="Leroux, Frederic R" uniqKey="Leroux F" first="Frédéric R." last="Leroux">Frédéric R. Leroux</name>
<name sortKey="Leroux, Frederic R" sort="Leroux, Frederic R" uniqKey="Leroux F" first="Frédéric R." last="Leroux">Frédéric R. Leroux</name>
<name sortKey="Leroux, Frederic R" sort="Leroux, Frederic R" uniqKey="Leroux F" first="Frédéric R." last="Leroux">Frédéric R. Leroux</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Lorraine/explor/LrgpV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000B65 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000B65 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Lorraine
   |area=    LrgpV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     ISTEX:00B8AE2CC871EF51AC29C430B984F3C1652C9528
   |texte=   Efficient and Complementary Methods Offering Access to Synthetically Valuable 1,2‐Dibromobenzenes
}}

This area was generated with Dilib version V0.6.32.
Data generation: Sat Nov 11 15:47:48 2017. Site generation: Wed Mar 6 23:31:34 2024

	Serveur d'exploration sur le LRGP
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le LRGP

Efficient and Complementary Methods Offering Access to Synthetically Valuable 1,2‐Dibromobenzenes

Efficient and Complementary Methods Offering Access to Synthetically Valuable 1,2‐Dibromobenzenes

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri